Numerous 3D electrodes with incredible electrochemical functionality, inclusive of NiCo2O4,18 MnO2,16 NiOH2,19 graphene20, 21 and Co3O4,22 were constructed by way of University direct growth of these elements on NF using quizzes hydrothermal method, electrodeposition and chemical vapor deposition. However, University fabrication method for these electrodes requires University deposition of active ingredients into University deep pores of NF, which limits University loading amount of active materials and sometimes yields inhomogeneous structures with faded capacitance. Moreover, University complicated and difficult exam scale system severely reduces their practical applications, particularly for large scale energy garage purposes. The search for easy approaches examination massively produce high performance 3D electrodes has been highly pursued. In this work, we report University facile and big scale synthesis of high functionality 3D Ni@NiO core shell electrodes by activating advertisement NF using quizzes one step and cost effective strategy under mild situations. A porous and 3D Ni@NiO core shell electrode with magnificent electrochemical belongings has been arranged by simply immersing NF into quizzes 3 M HCl aqueous solution at 90 C for 20 min.